Lucario

The 2013 XY Black Star Promos Lucario is a promo Fighting-type Pokémon card with 100 HP, evolving from Riolu, illustrated by Naoki Saito. Raw near-mint copies trade around $9.98, while a PSA 10 is modelled near $59.88 and a PSA 9 near $27.98. In its original set it is a chase card — roughly a 1-in-332 booster pull (modelled, not official). Lucario has 12 other printings in the catalogue.